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ruta_chalepensis_l [2021/10/21 10:19]
andreas 		ruta_chalepensis_l [2021/10/21 10:56] (aktuell)
andreas
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-A solvent extract of sulfurous-sweaty smelling Ruta chalepensis contained 21 related organic sulfur-containing compounds, from which 19 were confirmed by comparison of their analytical data with those of authentic reference samples. These compounds belong to a family of natural flavor molecules having a 1,3-positioned O,S moiety in common like 1-methoxyhexane-3-thiol (known from Salvia sclarea) and 4-methyl-3-sulfanylhexan-1-ol e.g. The natural isomers of 4-methyl-3-sulfanylhexan-1-ol consisted of a 65:35 mixture of the (3R,4S)-isomer (onion, garlic, perspiration) and the (3S,4S)-isomer (weaker, not much character). The unnatural isomer (3R,4R) was described as "rhubarb, green, and very natural grapefruit" by a chirospecific GC-sniffing experiment. \\+A solvent extract of sulfurous-sweaty smelling Ruta chalepensis contained 21 related organic sulfur-containing compounds, from which 19 were confirmed by comparison of their analytical data with those of authentic reference samples. These compounds belong to a family of natural flavor molecules having a 1,3-positioned O,S moiety in common like 4-methoxy-2-methylbutane-2-thiol (main sulfur containing component), 1-methoxyhexane-3-thiol (known from Salvia sclarea) and 4-methyl-3-sulfanylhexan-1-ol e.g. The natural isomers of 4-methyl-3-sulfanylhexan-1-ol consisted of a 65:35 mixture of the (3R,4S)-isomer (onion, garlic, perspiration) and the (3S,4S)-isomer (weaker, not much character). The unnatural isomer (3R,4R) was described as "rhubarb, green, and very natural grapefruit" by a chirospecific GC-sniffing experiment. \\
 [Escher, Sina, et al. "Combinatorial Synthesis by Nature: Volatile Organic Sulfur‐Containing Constituents of Ruta chalepensis L." Chemistry & biodiversity 3.9 (2006): 943-957] [Escher, Sina, et al. "Combinatorial Synthesis by Nature: Volatile Organic Sulfur‐Containing Constituents of Ruta chalepensis L." Chemistry & biodiversity 3.9 (2006): 943-957]
  
ruta_chalepensis_l.txt · Zuletzt geändert: 2021/10/21 10:56 von andreas

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