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pogostemon_cablin_blanco_benth [2017/05/23 09:07]
andreas |
pogostemon_cablin_blanco_benth [2022/09/30 09:34] (aktuell)
andreas |
| [GC-FTIR and GC-MS in odour analysis of essential oils., Nikiforov, A., Jirovetz, L., Buchbauer, G., Raverdino, V., Microchimica Acta, Vol.95(1-6), 1988, 193-198] | [GC-FTIR and GC-MS in odour analysis of essential oils., Nikiforov, A., Jirovetz, L., Buchbauer, G., Raverdino, V., Microchimica Acta, Vol.95(1-6), 1988, 193-198] |
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| Rotundone with its very low recognition threshold value is a constituent of patchouli oil. \\ | Rotundone is a trace constituent of patchouli oil with impact on its scent due to its very low recognition treshold value.\\ |
| [Meaningful Scents around the World, Roman Kaiser, Zürich 2006, 63] | [Meaningful Scents around the World, Roman Kaiser, Zürich 2006, 63] |
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| Main components of supercritical CO2 extracts of patchouli leaves from Brazil (yield 0.44-5.0%) were β-patchoulene (1.6-3.2%), β-caryophyllene (3.1-5.8%), α-guaiene (13.3-24.1%), α-patchoulene (4.5-6.2%), seychellene (1.7-2.3%), δ-guaiene (15.5-21.1%), and patchoulol (12.9-32.2%). \\ | Main components of supercritical CO2 extracts of patchouli leaves from Brazil (yield 0.44-5.0%) were β-patchoulene (1.6-3.2%), β-caryophyllene (3.1-5.8%), α-guaiene (13.3-24.1%), α-patchoulene (4.5-6.2%), seychellene (1.7-2.3%), δ-guaiene (= α-bulnesene, 15.5-21.1%), and patchoulol (12.9-32.2%). \\ |
| [Comparison of extraction of patchouli (Pogostemon cablin) essential oil with supercritical CO2 and by steam distillation., Donelian, A., Carlson, L.H.C., Lopes, T.J., Machado, R.A.F., The Journal of Supercritical Fluids, 48(1), 15-20, 2009] | [Comparison of extraction of patchouli (Pogostemon cablin) essential oil with supercritical CO2 and by steam distillation., Donelian, A., Carlson, L.H.C., Lopes, T.J., Machado, R.A.F., The Journal of Supercritical Fluids, 48(1), 15-20, 2009] |
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| [Composition and comparison of essential oils of Pogostemon cablin (Blanco) Benth.(Patchouli) and Pogostemon travancoricus Bedd. var. travancoricus., Sundaresan, V., Singh, S.P., Mishra, A.N., Shasany, A.K., Darokar, M.P., Kalra, A., Naqvi, A.A., Journal of Essential Oil Research, 21(3), 2009, 220-222] [[http://staff.cimap.res.in/PublicationFiles/JEOR.pdf]] | [Composition and comparison of essential oils of Pogostemon cablin (Blanco) Benth.(Patchouli) and Pogostemon travancoricus Bedd. var. travancoricus., Sundaresan, V., Singh, S.P., Mishra, A.N., Shasany, A.K., Darokar, M.P., Kalra, A., Naqvi, A.A., Journal of Essential Oil Research, 21(3), 2009, 220-222] [[http://staff.cimap.res.in/PublicationFiles/JEOR.pdf]] |
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| "The primary fragrance molecule in the essential oil is the sesquiterpene alcohol norpatchoulenol, which is present at 0.35-1.0% or less" [Flavours and Fragrances: Chemistry, Bioprocessing and Sustainability. Ralf Günter Berger, Springer 2010] | "The primary fragrance molecule in the essential oil is the sesquiterpene alcohol norpatchoulenol, which is present at 0.35-1.0% or less." \\ |
| | [Flavours and Fragrances: Chemistry, Bioprocessing and Sustainability. Ralf Günter Berger, Springer 2010] |
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| |{{patchoulol.jpg}} \\ (−)-patchoulol \\ //(typical patchouli, th 0.93ng/l air)// | {{norpatchoulenol.jpg}} \\ (+)-norpatchoulenol \\ //(typical patchouli, th 2.8ng/l air)//| | |{{patchoulol.jpg}} \\ (−)-patchoulol \\ //(typical patchouli, th 0.93ng/l air)// | {{norpatchoulenol.jpg}} \\ (+)-norpatchoulenol \\ //(typical patchouli, th 2.8ng/l air)//| {{nortetracyclopatchoulol.jpg}} \\ (+)-nortetracyclopatchoulol \\ //(typical patchouli, th 1.0ng/l air)//| |
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| Major constituent of the essential oil produced by steam distillation of the dried leaves is (-)-patchoulol (patchouli alcohol, 23.6-45.9%), whereas (+)-norpatchoulenol is only 0.5%. "The dispute about the olfactory properties of [[http://www.leffingwell.com/chirality/patchoulol.htm|(-)-patchoulol]] was settled by Näf et al. by the stereoselective synthesis of both enantiomeric forms of (-)-patchoulol, which established (the molecule) to possess a typical patchouli note... whereas the non-natural ent(+)-enantiomer has a much weaker odor, and is not reminescent of patchouli oil... while (+)-norpatchoulenol was about three times less potent with an odor treshold of ca. 2.8ng/l air... The approximate treshold figures are due to vastly diverging sensitivities and a large number of anosmias for pathcouli odorants. The inability of many people to smell some of the patchouli odorants may well have caused the dispute in the first place." \\ | Major constituent of the essential oil produced by steam distillation of the dried leaves is (-)-patchoulol (patchouli alcohol, 23.6-45.9%), whereas (+)-norpatchoulenol comprises only 0.5%. \\ |
| | "The dispute about the olfactory properties of [[http://www.leffingwell.com/chirality/patchoulol.htm|(-)-patchoulol]] was settled by Näf et al. by the stereoselective synthesis of both enantiomeric forms of (-)-patchoulol, which established (the molecule) to possess a typical patchouli note... whereas the non-natural ent(+)-enantiomer has a much weaker odor, and is not reminescent of patchouli oil... while (+)-norpatchoulenol was about three times less potent with an odor treshold of ca. 2.8ng/l air... The approximate treshold figures are due to vastly diverging sensitivities and a large number of anosmias for patchouli odorants. The inability of many people to smell some of the patchouli odorants may well have caused the dispute in the first place." \\ |
| [Scent and Chemistry, Günther Ohloff, Wilhelm Pickenhagen, Philip Kraft, Wiley-VCH, 2012] | [Scent and Chemistry, Günther Ohloff, Wilhelm Pickenhagen, Philip Kraft, Wiley-VCH, 2012] |
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| | When the headspace, rather than the oil, is subjected to GC analysis, a series of highly volatile compounds that have never been described in patchouli oil were found to be significant contributors to some of the odour nuances of patchouli oil. Compounds included 2-ethyl furan, 4-ethenyl-2-methoxyphenol (4-vinyl guaiacol), ethyl 4-methylvalerate, (4S,4aS,8aR)-4,8a-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-4a-ol (geosmin), 4-ethyl-2-methoxyphenol (4-ethyl guaiacol), 4-ethyl phenol, 2,6,6-trimethylcyclohexa-1,3-dienecarbaldehyde (safranal), 3-propyl phenol, iso-butyl methoxy pyrazine, 2-methoxy-3,6-dimethyl pyrazine, and 1,2,7,7- tetramethylbicyclo[2.2.1]heptan-2-ol (2-methyl isoborneol). \\ |
| | [Givaudan, Perfume compositions, World Patent 2017/050971, September 24, 2015] [[https://encrypted.google.com/patents/WO2017050971A1]] |
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| | Average concentration (GC, internal normalisation) of major patchouli constituents based on over 100 patchouli oils were e.g. (ranges and ISO 2003 norm in parenthesis): patchoulol 39% (11-72%, ISO 27-35%), norpatchoulenol 0.86% (0.11‐4.0%, ISO 0.35-1%), α‐bulnesene 14% (2.9‐23%, ISO 13-21%), α‐guaiene 11% (2.9‐23%, ISO 11-16%). (+)-Nortetracyclopatchoulol "...is not necessarlily a 0.001% trace constituent but can occur at concentrations of 0.5% or higher. Therefore, in some oils it might contribute significantly to the overall patchouli odour... The presence of rotundone in PEO [patchouli essential oil] is not surprising since it has been shown to be readily produced by aerial oxidation of α‐guaiene... The detection thresholds measured for the three closely related tertiary alcohols are important parameters to consider when discussing their odour value and relative contributions: (−)‐patchoulol ~0.93 ng/L air, (+)‐norpatchoulenol ~2.8 ng/L air, (+)‐nortetracyclopatchoulol: ~1.0 ng/L air...Pogostol has been mentioned once as one of the major contributors to the woody odour of PEO but this seems somewhat doubtful... Cis- and trans-pentylcyclopropane carboxylic acids, respectively cis-2-pentylcyclopropanecarboxylic acid and trans-2-pentylcyclopropanecarboxylic acid, are potent odour contributors: when isolated, the cis-isomer, which occurs in the essential oil at ~200 ppm, is claimed to possess a 'patchouli-like, animal, leathery note with good intensity and persistence'. The contribution of pogostone (syn. dhelwangin) that occurs - like its minor analogs - in variable concentrations in PEO, has not been reported so far, and is therefore supposed to be negligible or nil." \\ |
| | [van Beek TA, Joulain D. The essential oil of patchouli, Pogostemon cablin: A review. Flavour Fragr J. 2017;1-45] \\ |
| | [[http://onlinelibrary.wiley.com/doi/10.1002/ffj.3418/pdf]] |
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| | {{pogostemoncablin_magdeburg2022.jpg?800}} \\ |
| | Pogostemon cablin. Gruson Gewächshäuser Magdeburg (2022) \\ |
| | [[https://creativecommons.org/licenses/by-sa/3.0/de/|CC BY-SA 3.0]], Author: Andreas Kraska |
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| {{:pogostemon_cablin.jpg?800}}\\ | {{:pogostemon_cablin.jpg?800}}\\ |
| [[https://creativecommons.org/licenses/by-sa/3.0/de/|CC BY-SA 3.0]], Author: Forest & Kim Starr [[https://commons.wikimedia.org/wiki/File:Starr_070906-8832_Pogostemon_cablin.jpg|Wikimedia Commons]] | [[https://creativecommons.org/licenses/by-sa/3.0/de/|CC BY-SA 3.0]], Author: Forest & Kim Starr [[https://commons.wikimedia.org/wiki/File:Starr_070906-8832_Pogostemon_cablin.jpg|Wikimedia Commons]] |
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| [[https://www.youtube.com/watch?v=YyX77AVHCD4|Extern video: The Journey of Patchouli - Givaudan ]] | [[https://www.youtube.com/watch?v=YyX77AVHCD4|video (external): The Journey of Patchouli - Givaudan® ]] |
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| | [[http://www.restek.com/chromatogram/view/GC_FF00849/514-51-2| (external): Patchouli Oil Rtx®-5Sil MS by GC/MS - Restek® ]] |
