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juniperus_virginiana_l [2017/08/16 20:44]
andreas
juniperus_virginiana_l [2021/03/26 15:27] (aktuell)
andreas
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 [[http://en.wikipedia.org/wiki/Juniperus_virginiana]] [[http://en.wikipedia.org/wiki/Juniperus_virginiana]]
  
-Fractionation and analysis of Virginia cedarwood oil made clear that hydrocarbons (thujopsene, cedrene) and cedrol (week woody odor) hardly contribute to the specific odor of the oil. Fractions with woody, amber, phenolic, lactonic, and grapefruit aspects were found. Oxygenated sesquiterpenes like betulenal (with odor aspects of sandalwood and acetyl cedrene), funebrenal (8-cedren-15-al or α-cedrenal, woody), thujopsenal, chamigrenal, 8-cedren-10-one (musty, woody, mint, myrrh-like), and nootkatone (grapefruit-like) seem to contribute to the typical cedar character of the oil. \\+Red cedarwood oil possesses a soft, pleasant, balsamic typical cedarwood odor. Fractionation and analysis of Virginia cedarwood oil made clear that hydrocarbons (thujopsene, cedrene) and cedrol (week woody odor) hardly contribute to the specific odor of the oil. Fractions with woody, amber, phenolic, lactonic, and grapefruit aspects were found. Oxygenated sesquiterpenes like betulenal (with odor aspects of sandalwood and acetylcedrene), funebrenal (8-cedren-15-al or α-cedrenal, woody), thujopsenal, chamigrenal, 8-cedren-10-one (musty, woody, mint, myrrh-like), and nootkatone (grapefruit-like) seem to contribute to the typical cedarwood character of the oil. \\
 ["On the chemical composition of cedarwood oil (Juniperus virginiana L.).", Heide, R. T., Visser, J., Van der Linde, L. M., Van Lier, F. P., Developments in food science, 18, (1988), 627-637] ["On the chemical composition of cedarwood oil (Juniperus virginiana L.).", Heide, R. T., Visser, J., Van der Linde, L. M., Van Lier, F. P., Developments in food science, 18, (1988), 627-637]
  
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 Small trees have relatively low amounts of CWO because small trees have high percentages of sapwood which contains very low amounts of CWO compared to the heartwood"\\ Small trees have relatively low amounts of CWO because small trees have high percentages of sapwood which contains very low amounts of CWO compared to the heartwood"\\
 [Critical fluid extraction of //Juniperus virginiana// L. and bioactivity of extracts against subterranean termites and wood-rot fungi. Eller, F. J., Clausen, C. A., Green, F., & Taylor, S. L., Industrial crops and products, Vol.32(3), 2010, 481-485] [Critical fluid extraction of //Juniperus virginiana// L. and bioactivity of extracts against subterranean termites and wood-rot fungi. Eller, F. J., Clausen, C. A., Green, F., & Taylor, S. L., Industrial crops and products, Vol.32(3), 2010, 481-485]
 +
 +----
  
 "α-Cedrene and thujopsene are the main products of the sesquiterpene fraction of red cedarwood oil (Juniperus virginiana L., Cupressaceae). While these sesquiterpenes possess only weak and uncharacteristic odors, some oxygenated derivatives are widely used in perfumery. The most important volume is the acetylation product of the sequiterpene fraction, sold under trade names such as //Vertofix Coeur (IFF)//, //Lignofix (Symrise)//, and //Cedartone V (Givaudan)//. It possesses an intense woody, ambery odor, which is attributed to a content of 5-10% of [1-aceto-7,10-ethano-4,4,7-trimethyl-1(9)-octalin, [[http://www.thegoodscentscompany.com/data/rw1046821.html|CAS 32388-56-0]]] ...\\ "α-Cedrene and thujopsene are the main products of the sesquiterpene fraction of red cedarwood oil (Juniperus virginiana L., Cupressaceae). While these sesquiterpenes possess only weak and uncharacteristic odors, some oxygenated derivatives are widely used in perfumery. The most important volume is the acetylation product of the sequiterpene fraction, sold under trade names such as //Vertofix Coeur (IFF)//, //Lignofix (Symrise)//, and //Cedartone V (Givaudan)//. It possesses an intense woody, ambery odor, which is attributed to a content of 5-10% of [1-aceto-7,10-ethano-4,4,7-trimethyl-1(9)-octalin, [[http://www.thegoodscentscompany.com/data/rw1046821.html|CAS 32388-56-0]]] ...\\
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 [Acid-catalyzed isomerization of thujopsene., Kitchens, G. C., Daeniker, H. U., Hochstetler, A. R., Kaiser, K., The Journal of Organic Chemistry, Vol.37(1), 1972, 1-5] \\ [Acid-catalyzed isomerization of thujopsene., Kitchens, G. C., Daeniker, H. U., Hochstetler, A. R., Kaiser, K., The Journal of Organic Chemistry, Vol.37(1), 1972, 1-5] \\
 [Acetylation of thujopsene., Kitchens, G.C., Daeniker, H.U., Hochstetler, A.R., Kaiser, K., Blount, J. F., The Journal of Organic Chemistry, 37(1), 1972, 6-8] [Acetylation of thujopsene., Kitchens, G.C., Daeniker, H.U., Hochstetler, A.R., Kaiser, K., Blount, J. F., The Journal of Organic Chemistry, 37(1), 1972, 6-8]
 +
 +"As cedarwood oil (Juniperus virginiana L.) is a by-product of the American timber industry, it is one of the most economical and abundant sources of sesquiterpenes. This makes it an attractive starting material for the synthesis of other odorants like Vertofix®. On the other hand, any attempt to introduce a new cedarwood odorant is a lost cause, simply because cedarwood oil is so inexpensive. (+)-Cedrol (155) is responsible for its soft, woody odour, typical of cedarwood, and it is isolated from the oil by fractional distillation followed by crystallization." \\
 +[Fráter, Georg, Jerzy A. Bajgrowicz, and Philip Kraft. „Fragrance chemistry.“ Tetrahedron 54.27 (1998): 7633-7703]
  
 {{:juniperus_virginiana.jpg?600}} \\ {{:juniperus_virginiana.jpg?600}} \\
juniperus_virginiana_l.1502909046.txt.gz · Zuletzt geändert: 2017/08/16 20:44 von andreas