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daphne_mezereum_l [2015/06/17 14:41]
andreas
daphne_mezereum_l [2018/02/01 10:39] (aktuell)
andreas
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 Deciduous shrub, 0.40-1.20m high, native to Europe and Western Asia; flowers cauliflor, dark pink or sometimes white, produced in early spring before the leaves; fruits red, ovoid. Deciduous shrub, 0.40-1.20m high, native to Europe and Western Asia; flowers cauliflor, dark pink or sometimes white, produced in early spring before the leaves; fruits red, ovoid.
  
-"The floral fragrance of the shrub Daphne mezereum in central Sweden was collected by means of the head-space technique and investigated by GC-MS and multi-dimensional GC. (S)-(+)-Linalool was the main constituent (95%) of the flower fragrance and its enantiomeric purity exceeded 99% in the samples. The (2S, 5S)- and (2R, 5S)-furanoid and the (3R, 6S)- and (3S, 6S)-pyranoid linalool oxide isomers constituted 25% of the fragrance. "  \\+The main volatile compounds of a dynamic headspace concentrate from D.mezereum flowers were linalool (49%), (E)-β-ocimene (16%), 2-phenylethanol (4%), jasmone (3%), benzyl alcohol (2%), and cinnamic alcohol (0.3%). \\ 
 +[Volatile constituents of European bird cherry flowers (Padus avium Mill.). Surburg, H., Güntert, M., Schwarze, B.,Journal of Essential Oil Research, Vol.2(6), 1990, 307-316]  
 + 
 +"The floral fragrance of the shrub Daphne mezereum in central Sweden was collected by means of the head-space technique and investigated by GC-MS and multi-dimensional GC. (S)-(+)-Linalool was the main constituent (95%) of the flower fragrance and its enantiomeric purity exceeded 99% in the samples. The (2S,5S)- and (2R,5S)-furanoid and the (3R,6S)- and (3S,6S)-pyranoid linalool oxide isomers constituted 2-5% of the fragrance."  \\
 [Floral fragrance chemistry in the early flowering shrub //Daphne mezereum//. Borg-Karlson, A. K., Unelius, C. R., Valterová, I., Anders Nilsson, L., Phytochemistry, Vol.41(6), 1996, 1477-1483] [Floral fragrance chemistry in the early flowering shrub //Daphne mezereum//. Borg-Karlson, A. K., Unelius, C. R., Valterová, I., Anders Nilsson, L., Phytochemistry, Vol.41(6), 1996, 1477-1483]
 +
 +{{:linalool_isomers.jpg|}} \\ 
 +[[http://www.leffingwell.com/chirality/linalool.htm|linalool stereo isomers]]: (S)-(+)-linalool (coriandrol: sweet, floral) and (R)-(-)-linalool (licareol: floral, woody lavender)
  
 The main volatile compounds from D.mezereum flower scent, collected by the dynamic headspace method, were linalool (85.6%), (E)-β-ocimene (6.7%), hexadecane (3.7%), benzyl alcohol (0.9%), (E,E)-α-farnesene (0.7%), lavandulol (0.5%), (Z)-β-ocimene (0.6%), cinnamic alcohol (0.4%) and 2-phenylethanol (0.4%). \\ The main volatile compounds from D.mezereum flower scent, collected by the dynamic headspace method, were linalool (85.6%), (E)-β-ocimene (6.7%), hexadecane (3.7%), benzyl alcohol (0.9%), (E,E)-α-farnesene (0.7%), lavandulol (0.5%), (Z)-β-ocimene (0.6%), cinnamic alcohol (0.4%) and 2-phenylethanol (0.4%). \\
 [Floral scents in butterfly‐pollinated plants: possible convergence in chemical composition., Andersson, S., Nilsson, L.A., Groth, I., Bergström, G., Botanical Journal of the Linnean Society, 140(2), 2002, 129-153] [Floral scents in butterfly‐pollinated plants: possible convergence in chemical composition., Andersson, S., Nilsson, L.A., Groth, I., Bergström, G., Botanical Journal of the Linnean Society, 140(2), 2002, 129-153]
  
-{{:daphne_mezereumk.jpg|}} \\ +{{:daphne_mezereum.jpg?600}} \\ 
-Köhler,F.E., Medizinal Pflanzen, vol.1 t.26 (1887) [W.Müller] \\+Duhamel du Monceau,H.L., Traité des arbres et arbustes, Nouvelle édition [Nouveau Duhamel], vol.1 t.(1800-1803) [Redouté] \\
 [[http://plantgenera.org/species.php?id_species=320908]] [[http://plantgenera.org/species.php?id_species=320908]]
 +
 +
 +{{http://www.botanische-spaziergaenge.at/Bilder/Konica_1/PICT5632.JPG}} \\
 +Daphne mezereum \\ © Rolf Marschner (2005),  
 +[[http://botanische-spaziergaenge.at/viewtopic.php?f=449&t=1559| www.botanische-spaziergaenge.at]]
daphne_mezereum_l.1434544871.txt.gz · Zuletzt geändert: 2015/06/17 14:41 von andreas