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convallaria_majalis_l [2019/03/07 10:55]
andreas
convallaria_majalis_l [2022/01/08 21:59] (aktuell)
andreas
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 [Surburg et al., Volatile compounds from Flowers, in: Teranishi, R.;Buttery, R. G.;Sugisawa, H. Bioactive volatile compounds from plants. (Book) 1993, 169-186]  [Surburg et al., Volatile compounds from Flowers, in: Teranishi, R.;Buttery, R. G.;Sugisawa, H. Bioactive volatile compounds from plants. (Book) 1993, 169-186] 
  
-|{{citronellol.jpg| citronellol }} \\ citronellol| {{geraniol.jpg| geraniol }} \\ geraniol| {{e23dihydrofarnesol.jpg| (E)-2,3-dihydrofarnesol}} \\ (E)-2,3-dihydrofarnesol|+|{{:benzyl_alcohol.png| benzyl alcohol}} \\ benzyl alcohol |{{citronellol.jpg| citronellol }} \\ citronellol| {{geraniol.jpg| geraniol }} \\ geraniol| {{e23dihydrofarnesol.jpg| (E)-2,3-dihydrofarnesol}} \\ (E)-2,3-dihydrofarnesol|{{:ionone_beta.jpg| β-ionone}} \\ β-ionone |
  
-"The odorants could be divided into floral-rosy-citrusy notescitronellol (9.6%), geraniol (8.4%), nerol (1.3%), citronellyl acetate (1.1%), geranyl acetate (3.3%), geranial + benzyl acetate (0.96%), neral (0.02%), benzyl alcohol (35%), phenethyl alcohol (0.78%), phenylacetonitrile (3.0%), farnesol (1.9%) and 2,3-dihydrofarnesol (0.88 %)green-grassy notes(Z)-3-hexen-1-ol (11%), (Z)-3-hexenyl acetate (7.8%), (Z)-3-hexenal (trace) and (E)-2-hexenal (0.18%), green pea and galbanum-like notes: 2-isopropyl-3-methoxypyrazine (traceand 2-isobutyl-3-methoxypyrazine (trace)fatty, waxy, aldehydic notesoctanal (0.15%), nonanal (0.1 %), decanal (0.07%) and fruity, raspberry notesβ-ionone (trace)." \\ +GC-MS analysis of vacuum headspace samples of the flower scent showed main components with floral-rosy-citrusy notes like citronellal, citronellol (9.6%), citronellyl acetate (1.1%), geranyl acetate (3.3%), nerol (1.3%), geraniol (8.4%), benzyl alcohol (35.2%), phenylethyl alcohol (0.78%), geranial + benzyl acetate (0.96%), neral (0.02%),  phenylacetonitrile (3.0%), farnesol (1.9%) and 2,3-dihydrofarnesol (0.88 %)green-grassy notes like (Z)-3-hexen-1-ol (10.6%), (Z)-3-hexenyl acetate (7.8%), (E)-2-hexenal (0.18%), and (Z)-3-hexenal (trace)fatty, waxy, aldehydic notes like octanal (0.15%), nonanal (0.1 %), and decanal (0.07%). \\ 
-[[http://www.bojensen.net/EssentialOilsEng/EssentialOils17/EssentialOils17.htm]] \\+Important trace components could be revealed by GC sniffing analysis, like (Z)-3-hexenal, green pea and galbanum-like notes like 2-isopropyl-3-methoxypyrazine and 2-isobutyl-3-methoxypyrazineand fruity-raspberry notes like β-ionone. \\
 [New data on trace components with sensory relevance in flower scents, Brunke, E.J., Rittler, F., Schmaus, G., Dragoco Rep., 1, 1996, 5-21] [New data on trace components with sensory relevance in flower scents, Brunke, E.J., Rittler, F., Schmaus, G., Dragoco Rep., 1, 1996, 5-21]
 +
 +„…studies performed at Firmenich also revealed trace amounts of phenylacetaldehyde oxime, which exhibits an interesting muguet-orange flower duality when in pure form. It was proposed that its combination with 2,3-laevo-dihydrofarnesol could reproduce the key note of the flower; however, the instability of this oxime prevents its use on industrial scale.“ \\
 +[Coulomb, J. "Beyond muguet." Perfumer & Flavorist 43.4 (2018): 40-46]
 +
 +Main volatile constituents of a diethyl ether extract of C. majalis flowers from Serbia were benzyl alcohol, citronellol, geranyl acetate, 2,3-dihydrofarnesol, (E)-cinnamyl alcohol, and (E)- and (Z)-isomers of phenylacetaldehyde oxime. \\
 +[Đorđević, Miljana R. "PP94. Lily of the valley flower volatiles: the chemical composition of the flower diethyl ether extract."] \\
 +[[https://core.ac.uk/download/pdf/228560523.pdf]]
  
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-The standardised (effect correponding to 0.2% convallatoxin) powder of dried aboveground parts of C.majalis (Convallaria herba) is used against mild cardiac insuffiency. "Convallatoxin is similar to other cardiac glycosides. It inhibits Na+,K+ ATPase and indirectly increases intracellular Ca+ concentration.This strengthens the contraction of the heart muscle... The herb is very toxic and must only be administered under the supervision of a qualified practioner." \\+The standardised (effect corresponding to 0.2% convallatoxin) powder of dried aboveground parts of C.majalis (Convallaria herba) has been used to treat mild cardiac insuffiency. "Convallatoxin is similar to other cardiac glycosides. It inhibits Na+,K+ ATPase and indirectly increases intracellular Ca+ concentration.This strengthens the contraction of the heart muscle... The herb is very toxic and must only be administered under the supervision of a qualified practioner." \\
 [Medicinal Plants of the World. Ben-Erik Van Wyk and Michael Wink, Pretoria 2004, 112] [Medicinal Plants of the World. Ben-Erik Van Wyk and Michael Wink, Pretoria 2004, 112]
  
convallaria_majalis_l.1551952525.txt.gz · Zuletzt geändert: 2019/03/07 10:55 von andreas