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calocedrus_decurrens_torr._florin [2018/09/16 12:25]
andreas
calocedrus_decurrens_torr._florin [2022/06/05 11:57] (aktuell)
andreas
Zeile 13: Zeile 13:
 [The leaf essential oils of the genus Calocedrus., Adams, R.P., Nguyen, S., Hsieh, C.F., Kaiyun, G., Journal of Essential Oil Research, 18(6), 2006, 654-658] [The leaf essential oils of the genus Calocedrus., Adams, R.P., Nguyen, S., Hsieh, C.F., Kaiyun, G., Journal of Essential Oil Research, 18(6), 2006, 654-658]
  
-| {{:carene_d3.jpg| δ-3-carene }} \\ δ-3-carene | {{:limonene.jpg| limonene }} \\ limonene | {{:thymoquinone.jpg| thymoquinone }} \\ thymoquinone | {{:carvacrol.jpg| carvacrol }} \\ carvacrol |+(3E,5Z)-undecatriene (0.3%) was a key odorant in headspace samples of Calocedrus decurrens leaves. \\ 
 +[Scent of a vanishing flora, Roman Kaiser, 2011, 170]  
 + 
 +|{{:carene_d3.jpg| δ-3-carene }} \\ δ-3-carene |{{:limonene.jpg| limonene }} \\ limonene |{{:3e5zundecatrien.jpg}} \\ (3E,5Z)-undecatriene |{{:thymoquinone.jpg| thymoquinone }} \\ thymoquinone |{{:carvacrol.jpg| carvacrol }} \\ carvacrol |
  
 Steam distillation of C.decurrens heartwood gave 0.6% of an essential oil composed mainly of derivatives of p-cymene and p-menthane. Thymoquinone (35.9%), carvacrol (29.2%), p-methoxythymol (11.0%) and p-methoxycarvacrol (3.2%) were the main components. "The tropolone [[http://www.thegoodscentscompany.com/data/rw1044801.html|beta-thujaplicin]] (hinokitiol) was only present in trace amounts. The high concentrations of thymoquinone and carvacrol alone can account for the previously observed high bioactivity of this oil. Carvacrol is well known for its antimicrobial, antioxidant, insecticidal, and repellent activities." \\ Steam distillation of C.decurrens heartwood gave 0.6% of an essential oil composed mainly of derivatives of p-cymene and p-menthane. Thymoquinone (35.9%), carvacrol (29.2%), p-methoxythymol (11.0%) and p-methoxycarvacrol (3.2%) were the main components. "The tropolone [[http://www.thegoodscentscompany.com/data/rw1044801.html|beta-thujaplicin]] (hinokitiol) was only present in trace amounts. The high concentrations of thymoquinone and carvacrol alone can account for the previously observed high bioactivity of this oil. Carvacrol is well known for its antimicrobial, antioxidant, insecticidal, and repellent activities." \\
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 α-pinene (729; woody resinous), acetic acid (243, vinegar-like), (Z)-non-2-enal (243; fatty), (E)-non-2-enal (243; fatty), fenchol (729; moldy), butanoic acid (81; cheesy), 3-methylbutanoic acid (729; cheesy), (E,E)-nona-2,4-dienal (729; fatty), (E,E)-deca-2,4-dienal (81; fatty), β-damascenone (81; apple juice-like), hexanoic acid (81; sweet musty metallic), γ-octalactone (243; sweet coconut-like), p-cresol (729; horse-like), sotolone (729; spicy savory), α-bisabolol (729; pepper-like), phenylacetic acid (243; honey-like), vanillin (729; vanilla), 3-phenylpropanoic acid (729; fruity sweet metallic), unknown (sweaty perfume-like, androstenone-like), unknown-tentavely thunbergol (729; gingerbread-like), thymoquinone (243; pencil-like). \\ α-pinene (729; woody resinous), acetic acid (243, vinegar-like), (Z)-non-2-enal (243; fatty), (E)-non-2-enal (243; fatty), fenchol (729; moldy), butanoic acid (81; cheesy), 3-methylbutanoic acid (729; cheesy), (E,E)-nona-2,4-dienal (729; fatty), (E,E)-deca-2,4-dienal (81; fatty), β-damascenone (81; apple juice-like), hexanoic acid (81; sweet musty metallic), γ-octalactone (243; sweet coconut-like), p-cresol (729; horse-like), sotolone (729; spicy savory), α-bisabolol (729; pepper-like), phenylacetic acid (243; honey-like), vanillin (729; vanilla), 3-phenylpropanoic acid (729; fruity sweet metallic), unknown (sweaty perfume-like, androstenone-like), unknown-tentavely thunbergol (729; gingerbread-like), thymoquinone (243; pencil-like). \\
 [Schreiner, Linda, Helene M. Loos, and Andrea Buettner. "Identification of odorants in wood of Calocedrus decurrens (Torr.) Florin by aroma extract dilution analysis and two-dimensional gas chromatography-mass spectrometry/olfactometry." Analytical and bioanalytical chemistry 409.15 (2017): 3719-3729] [Schreiner, Linda, Helene M. Loos, and Andrea Buettner. "Identification of odorants in wood of Calocedrus decurrens (Torr.) Florin by aroma extract dilution analysis and two-dimensional gas chromatography-mass spectrometry/olfactometry." Analytical and bioanalytical chemistry 409.15 (2017): 3719-3729]
 +
 +Using stable isotope dilution analysis (SIDA) and odor activity values (OAVs) calculated on the basis of odor thresholds determined in cellulose, hexanal, octanal, (E)-non-2-enal, p-cresol, vanillin, and thymoquinone were the dominant odorants for wood odor of several softwood species (Pinus sylvestris, Larix decidua, Calocedrus decurrens, Abies concolor, and Picea abies). Incense cedar wood with the mainly pencil-like,
 +eucalyptus-like odor was rated different from pine, larch, and spruce odor. The odor impression vinegar-like, which is characteristic for acetic acid, was rated as the most intense in the incense cedar. \\
 +"Regarding the quantitative results of thymoquinone, it is striking that its content was higher in the incense cedar wood at the same time being the only sample exceeding the odor threshold in cellulose (OAV = 4). This finding stands in line with the strong pencil-like odor perceived during the sensory evaluation. The odorant occurs in a 2500 times higher concentration in the incense cedar (1.1 g/kg) compared to the next
 +highest value of 416 μg/kg in the Scots pine sample." \\
 +[Schreiner, Linda, Eva Ortner, and Andrea Buettner. "Nosy confirmation: reconstitution of the characteristic odor of softwood via quantitative analysis and human sensory evaluation." Analytical and Bioanalytical Chemistry (2019): 1-13]
    
 {{:calocedrus_decurrens.jpg?600}} \\ {{:calocedrus_decurrens.jpg?600}} \\
 Sargent,C.S., The Silva of North America, vol.10 t.534 (1898) [C.E. Faxon] \\ Sargent,C.S., The Silva of North America, vol.10 t.534 (1898) [C.E. Faxon] \\
 [[http://plantgenera.org/species.php?id_species=181238]] [[http://plantgenera.org/species.php?id_species=181238]]
- 
  
 {{http://www.botanische-spaziergaenge.at/Bilder/Konica_2/PICT3313.JPG}} \\ {{http://www.botanische-spaziergaenge.at/Bilder/Konica_2/PICT3313.JPG}} \\
 Calocedrus decurrens, Schlosspark Schönbrunn \\ © Rolf Marschner (2006),   Calocedrus decurrens, Schlosspark Schönbrunn \\ © Rolf Marschner (2006),  
 [[http://botanische-spaziergaenge.at/viewtopic.php?f=219&t=448| www.botanische-spaziergaenge.at]] [[http://botanische-spaziergaenge.at/viewtopic.php?f=219&t=448| www.botanische-spaziergaenge.at]]
calocedrus_decurrens_torr._florin.1537093540.txt.gz · Zuletzt geändert: 2018/09/16 12:25 von andreas