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angelica_archangelica_l [2017/11/08 12:49]
andreas
angelica_archangelica_l [2019/02/19 17:52]
andreas
Zeile 16: Zeile 16:
 [Characterization of the Macrolide Fraction of Angelica Root Oil and Enantiomeric Composition of 12-Methyl-13-tridecanolide. Schultz, K., Kraft, P., Journal of Essential Oil Research, Vol.9(5), 1997, 509-514] [Characterization of the Macrolide Fraction of Angelica Root Oil and Enantiomeric Composition of 12-Methyl-13-tridecanolide. Schultz, K., Kraft, P., Journal of Essential Oil Research, Vol.9(5), 1997, 509-514]
  
-|{{:tridecanolide.jpg| tridecanolide }} \\ tridecanolide (C13)|{{:tridecanolide_12methyl.jpg| (12-methyl-13-tridecanolide }} \\ 12-methyl-13-tridecanolide (C13)|{{:exaltolide.jpg| exaltolide}} \\ exaltolide (C15)|+|{{:tridecanolide.jpg| tridecanolide }} \\ tridecanolide (C13) \\ //(cedarwood camphor)//|{{:tridecanolide_12methyl.jpg| (12-methyl-13-tridecanolide }} \\ 12-methyl-13-tridecanolide (C13) \\ //(12R)-(+) musky, sandalwood, pear // \\ //(12S)-(-) musky, animalic, camphor //|{{:exaltolide.jpg| exaltolide}} \\ exaltolide (C15) \\ //(sweet powdery musk)// |
  
 "Roots and seeds of Angelica archangelica L. were collected from different localities in western, eastern and northern Finnish Lapland. Two root samples and 33 seed samples were extracted with n-hexane and analysed by GC-MS using a chiral β-cyclodextrin phase. Major compounds in the root oils were (−)-α-pinene (19-42%) and (+)-sabinene (21-28%). One of the oils contained 22% (+)-3-carene but the other one had none at all. The seed oils were dominated by (−)-β-phellandrene (>60%). Other major compounds were (+)-sabinene, (+)-α-pinene, myrcene, (−)-α-phellandrene, (−)-α-pinene and (−)-limonene. Some statistically significant differences between seed samples from different localities could also be found." \\ "Roots and seeds of Angelica archangelica L. were collected from different localities in western, eastern and northern Finnish Lapland. Two root samples and 33 seed samples were extracted with n-hexane and analysed by GC-MS using a chiral β-cyclodextrin phase. Major compounds in the root oils were (−)-α-pinene (19-42%) and (+)-sabinene (21-28%). One of the oils contained 22% (+)-3-carene but the other one had none at all. The seed oils were dominated by (−)-β-phellandrene (>60%). Other major compounds were (+)-sabinene, (+)-α-pinene, myrcene, (−)-α-phellandrene, (−)-α-pinene and (−)-limonene. Some statistically significant differences between seed samples from different localities could also be found." \\
Zeile 33: Zeile 33:
 "The roots of Angelica archangelica L. were collected in three habitats (12 samples) in 1995-2002. The oils were analyzed by GC and GC/MS. The dominant component was α-pinene (15.7-20.8%) for two localities. Other three main constituents were δ-3-carene (15.4-16.9%), limonene (8.0-9.2%), sabinene (5.0-7.5%) for the first locality, and δ-phellandrene (13.5-15.4%), δ-3-carene (13.2-14.2%) and α-phellandrene (8.0-9.1%) for the second locality. The dominant oil components in the third locality were β-phellandrene (13.8-18.5%) together with α-pinene (11.4-15.0%), δ-3-carene (10.8-11.9%), α-cymene (6.8-10.6%) and α-phellandrene (5.9-8.6%). The oils contained 67.3-79.9% monoterpenoids (monoterpene hydrocarbons made up 60.2-72.6%), 9.6-19.4% sesquiterpenoids, 3.9-6.3% macrocyclic lactones and 1.2-5.3% coumarin osthol. Identified compounds (81 from 96) made up 91.4-99.2% of the oils." \\ "The roots of Angelica archangelica L. were collected in three habitats (12 samples) in 1995-2002. The oils were analyzed by GC and GC/MS. The dominant component was α-pinene (15.7-20.8%) for two localities. Other three main constituents were δ-3-carene (15.4-16.9%), limonene (8.0-9.2%), sabinene (5.0-7.5%) for the first locality, and δ-phellandrene (13.5-15.4%), δ-3-carene (13.2-14.2%) and α-phellandrene (8.0-9.1%) for the second locality. The dominant oil components in the third locality were β-phellandrene (13.8-18.5%) together with α-pinene (11.4-15.0%), δ-3-carene (10.8-11.9%), α-cymene (6.8-10.6%) and α-phellandrene (5.9-8.6%). The oils contained 67.3-79.9% monoterpenoids (monoterpene hydrocarbons made up 60.2-72.6%), 9.6-19.4% sesquiterpenoids, 3.9-6.3% macrocyclic lactones and 1.2-5.3% coumarin osthol. Identified compounds (81 from 96) made up 91.4-99.2% of the oils." \\
 [The chemical composition of the essential oil of Angelica archangelica L. roots growing wild in Lithuania. Nivinskienė, O., Butkienė, R., Mockutė, D., Journal of essential oil research, Vol.17(4), 2005, 373-377] [The chemical composition of the essential oil of Angelica archangelica L. roots growing wild in Lithuania. Nivinskienė, O., Butkienė, R., Mockutė, D., Journal of essential oil research, Vol.17(4), 2005, 373-377]
 +
 +Whereas 12-methyl-13-tridecanolide smells musky, the parent 14-membered macrolide tridecano-13-lactone (tridecanolide) does not. Moreover, also the enantiomers (which occure together in Angelica root oil with and R/S ratio of 72:28) "...differ significantly in their odor character: while the (+)-(12R)-isomer posesses a strong clean musk odor with sandalwood-like and fruity aspects, the enantiomer (-)-(12S) emanates an animalic musk odor with camphoraceous aspects." \\
 +[Kraft, Philip. Perspectives in flavor and fragrance research. John Wiley & Sons, 2005, 132-133]
  
 "The largest part of the essential oil from A. archangelica L. roots was composed of monoterpene hydrocarbons. α-pinene was found as a dominant constituent in more than half of the investigated plant oils obtained from Finland, Norway, France, and Brazil. Other dominant components such as β-phellandrene, δ-3-carene, and "The largest part of the essential oil from A. archangelica L. roots was composed of monoterpene hydrocarbons. α-pinene was found as a dominant constituent in more than half of the investigated plant oils obtained from Finland, Norway, France, and Brazil. Other dominant components such as β-phellandrene, δ-3-carene, and
angelica_archangelica_l.txt · Zuletzt geändert: 2022/06/08 21:01 von andreas