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angelica_archangelica_l [2019/08/12 18:37]
andreas
angelica_archangelica_l [2022/06/08 21:01] (aktuell)
andreas
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 Stout perennial 1.20-2.50m tall, native to noerthern Europe and Northwest Asia; leaves biternate, the lower leaves sometimes 30-90 cm long; segments oval, unevenly toothed or cut, terminal segments usually 3-lobed; umbels 8-15 cm across, with 20-40 rays; umbellets subtended by many linear bractlets.  Stout perennial 1.20-2.50m tall, native to noerthern Europe and Northwest Asia; leaves biternate, the lower leaves sometimes 30-90 cm long; segments oval, unevenly toothed or cut, terminal segments usually 3-lobed; umbels 8-15 cm across, with 20-40 rays; umbellets subtended by many linear bractlets. 
  
-A.archangelica extracts are used extensively in the liquor industry as a flavoring in liquor such as boonekamp, benedictine, and chartreuse. \\ +A.archangelica extracts are used extensively in the liquor industry as a flavoring in liquor such as boonekamp, benedictine, and chartreuse. [[http://de.wikipedia.org/wiki/Arznei-Engelwurz]]
-[[http://de.wikipedia.org/wiki/Arznei-Engelwurz]]+
  
 "Angelica root is nowadays specifically recommended for the treatment of appetite loss, stomach cramps and flatulence... The pharmacology appears to be poorly known but the plant stimulates the flow of gastric juices and has definite antispasmodic and cholagogue activities." \\ "Angelica root is nowadays specifically recommended for the treatment of appetite loss, stomach cramps and flatulence... The pharmacology appears to be poorly known but the plant stimulates the flow of gastric juices and has definite antispasmodic and cholagogue activities." \\
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 "The volatile components isolated from the root of two wild angelica strains (Angelica archangelica L. var. Archangelica) grown in the northern Finland were compared with the garden angelica (var. Sativa) grown in the north and in the south of Finland. More than 80 compounds were determined in the Soxhlet extracts by gas chromatography, and 67 were identified by gas chromatographymass spectrometry. Large variability in the relative amounts of the compounds was found. β-Phellandrene was the main component in var. Archangelica and sabinene in var. Sativa. The relative proportion of both hydrocarbon monoterpenes and oxygenated monoterpenes was larger in var. Sativa cultivated in the north than in the south of Finland" \\ "The volatile components isolated from the root of two wild angelica strains (Angelica archangelica L. var. Archangelica) grown in the northern Finland were compared with the garden angelica (var. Sativa) grown in the north and in the south of Finland. More than 80 compounds were determined in the Soxhlet extracts by gas chromatography, and 67 were identified by gas chromatographymass spectrometry. Large variability in the relative amounts of the compounds was found. β-Phellandrene was the main component in var. Archangelica and sabinene in var. Sativa. The relative proportion of both hydrocarbon monoterpenes and oxygenated monoterpenes was larger in var. Sativa cultivated in the north than in the south of Finland" \\
 [Characterization of volatile composition and odor of angelica (Angelica archangelica subsp. archangelica L.) root extracts. Kerrola, K., Galambosi, B., Kallio, H., Journal of Agricultural and Food Chemistry, 42(9), 1994, 1979-1988]  [Characterization of volatile composition and odor of angelica (Angelica archangelica subsp. archangelica L.) root extracts. Kerrola, K., Galambosi, B., Kallio, H., Journal of Agricultural and Food Chemistry, 42(9), 1994, 1979-1988] 
 +
 +|{{:beta_phellandrene.jpg| (−)-β-phellandrene}} \\ (−)-β-phellandrene \\ //(fresh spicy)// |{{:tridecanolide.jpg| tridecanolide }} \\ tridecanolide (C13) \\ //(cedarwood camphor)//|{{:tridecanolide_12methyl.jpg| (12-methyl-13-tridecanolide }} \\ 12-methyl-13-tridecanolide (C13) \\ //(12R)-(+) musky, sandalwood, pear // \\ //(12S)-(-) musky, animalic, camphor //|{{:exaltolide.jpg| exaltolide}} \\ exaltolide (C15) \\ //(sweet powdery musk)// |
  
 Angelica root oil contains a small fraction of musk-smelling macrolides. In this fraction the ω-alkanolides C13 (50.0%), C14 (0.5%), [[http://www.thegoodscentscompany.com/data/rw1004211.html|C15]] (42.0%, Exaltolide®), C16 (trace), and C17 (3-5%) as well as [[http://www.leffingwell.com/chirality/methyltridecanolide.htm|12-methyl-13-tridecanolide]] (4.0%) were identified. The enantiomeric composition was found to be 72.4 % (12R)-(+)-12-methyl-13-tridecanolide (musky, sandalwood, pear) and 27.6 % (12S)-(-)-12-methyl-13-tridecanolide (musky, animalic, camphor). \\ Angelica root oil contains a small fraction of musk-smelling macrolides. In this fraction the ω-alkanolides C13 (50.0%), C14 (0.5%), [[http://www.thegoodscentscompany.com/data/rw1004211.html|C15]] (42.0%, Exaltolide®), C16 (trace), and C17 (3-5%) as well as [[http://www.leffingwell.com/chirality/methyltridecanolide.htm|12-methyl-13-tridecanolide]] (4.0%) were identified. The enantiomeric composition was found to be 72.4 % (12R)-(+)-12-methyl-13-tridecanolide (musky, sandalwood, pear) and 27.6 % (12S)-(-)-12-methyl-13-tridecanolide (musky, animalic, camphor). \\
 [Characterization of the Macrolide Fraction of Angelica Root Oil and Enantiomeric Composition of 12-Methyl-13-tridecanolide. Schultz, K., Kraft, P., Journal of Essential Oil Research, Vol.9(5), 1997, 509-514] [Characterization of the Macrolide Fraction of Angelica Root Oil and Enantiomeric Composition of 12-Methyl-13-tridecanolide. Schultz, K., Kraft, P., Journal of Essential Oil Research, Vol.9(5), 1997, 509-514]
- 
-|{{:tridecanolide.jpg| tridecanolide }} \\ tridecanolide (C13) \\ //(cedarwood camphor)//|{{:tridecanolide_12methyl.jpg| (12-methyl-13-tridecanolide }} \\ 12-methyl-13-tridecanolide (C13) \\ //(12R)-(+) musky, sandalwood, pear // \\ //(12S)-(-) musky, animalic, camphor //|{{:exaltolide.jpg| exaltolide}} \\ exaltolide (C15) \\ //(sweet powdery musk)// | 
  
 "Roots and seeds of Angelica archangelica L. were collected from different localities in western, eastern and northern Finnish Lapland. Two root samples and 33 seed samples were extracted with n-hexane and analysed by GC-MS using a chiral β-cyclodextrin phase. Major compounds in the root oils were (−)-α-pinene (19-42%) and (+)-sabinene (21-28%). One of the oils contained 22% (+)-3-carene but the other one had none at all. The seed oils were dominated by (−)-β-phellandrene (>60%). Other major compounds were (+)-sabinene, (+)-α-pinene, myrcene, (−)-α-phellandrene, (−)-α-pinene and (−)-limonene. Some statistically significant differences between seed samples from different localities could also be found." \\ "Roots and seeds of Angelica archangelica L. were collected from different localities in western, eastern and northern Finnish Lapland. Two root samples and 33 seed samples were extracted with n-hexane and analysed by GC-MS using a chiral β-cyclodextrin phase. Major compounds in the root oils were (−)-α-pinene (19-42%) and (+)-sabinene (21-28%). One of the oils contained 22% (+)-3-carene but the other one had none at all. The seed oils were dominated by (−)-β-phellandrene (>60%). Other major compounds were (+)-sabinene, (+)-α-pinene, myrcene, (−)-α-phellandrene, (−)-α-pinene and (−)-limonene. Some statistically significant differences between seed samples from different localities could also be found." \\
 [Enantiomeric composition of monoterpene hydrocarbons in n‐hexane extracts of //Angelica archangelica// L. roots and seeds.Holm, Y., Vuorela, P., Hiltunen, R.,  Flavour and fragrance journal, Vol.12(6), 1997, 397-400] [Enantiomeric composition of monoterpene hydrocarbons in n‐hexane extracts of //Angelica archangelica// L. roots and seeds.Holm, Y., Vuorela, P., Hiltunen, R.,  Flavour and fragrance journal, Vol.12(6), 1997, 397-400]
  
-"A high content of β‐phellandrene (74.7%) was found in Angelica seed oilRoot oil contained a larger amount of macrocyclic lactones (1.3%) in comparison to the seed oil (0.4%). \\ +Main component of the pale yellow essential oil of the seeds (1.13%; strong peppery odor) was β‐phellandrene (74.7%). Other components were e.g. α-phellandrene, α-pinene, and linalool.  A small amount of macrocyclic lactones was found in the seed oil including tridecano‐13‐lactone (0.3%), pentadecano‐15‐lactone (0.2%), and heptadecano‐17‐lactone (trace). \\ 
-The highest‐boiling fraction of steam-distilled root oils contained 9.3% of macrocyclic lactones such as tridecano‐13‐lactone (5.0%), 12‐methyltridecano‐13‐lactone (0.4%), tetradecano‐14‐lactone (0.1%), pentadecano‐15‐lactone (3.5%), 14‐methylpentadecano‐15‐lactone (trace), hexadecano‐16‐lactone (trace), and heptadecano‐17‐lactone (0.2%). \\ +The essential oil of the roots contained a larger amount of macrocyclic lactones (1.3%) such as tridecano‐13‐lactone (0.65%), 12‐methyltridecano‐13‐lactone (0.06%), tetradecano‐14‐lactone (trace), pentadecano‐15‐lactone (0.53%), 14‐methylpentadecano‐15‐lactone (trace), hexadecano‐16‐lactone (trace), and heptadecano‐17‐lactone (0.06%). Main components of the root oil were β‐phellandrene (26.6%), α-phellandrene (19.1%), and α-pinene (15.7%). \\ 
-[Lopes, Daíse, Herbert Strobl, and Paul Kolodziejczyk. "14‐Methylpentadecano‐15‐lactone (Muscolide): A New Macrocyclic Lactone from the Oil of Angelica archangelica L." Chemistry & biodiversity 1.12 (2004): 1880-1887]+[Lopes, Daíse, Herbert Strobl, and Paul Kolodziejczyk. "14‐Methylpentadecano‐15‐lactone (Muscolide): A New Macrocyclic Lactone from the Oil of Angelica archangelica L." Chemistry & biodiversity 1.12 (2004): 1880-1887] \\ 
 +see also [Lopes, Daíse, Herbert Strobl, and Paul Kolodziejczyk. "14‐Methylpentadecano‐15‐lactone (Muscolide): A New Macrocyclic Lactone from the Oil of Angelica archangelica L." Perspectives in flavor and fragrance research. Ed. Karl AD Swift. Helvetica Chimica Acta, 2005, 47-53]
  
 Imperatorin is the most abundant furanocoumarin in the ethanolic seed extract of A.archangelica, comprising 40-50% of its total furanocoumarin content. Xanthotoxin is the second most abundant in the reaction mixture in the assay of the seed extract. The Acetylcholinesterase activity of imperatorin and xanthotoxin from Imperatorin is the most abundant furanocoumarin in the ethanolic seed extract of A.archangelica, comprising 40-50% of its total furanocoumarin content. Xanthotoxin is the second most abundant in the reaction mixture in the assay of the seed extract. The Acetylcholinesterase activity of imperatorin and xanthotoxin from
angelica_archangelica_l.txt · Zuletzt geändert: 2022/06/08 21:01 von andreas