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abies_balsamea_l._mill [2015/02/08 10:04]
andreas |
abies_balsamea_l._mill [2022/01/04 20:30] (aktuell)
andreas |
| [[http://www.efloras.org/florataxon.aspx?flora_id=1&taxon_id=233500002]] | [[http://www.efloras.org/florataxon.aspx?flora_id=1&taxon_id=233500002]] |
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| Steam distillation of foliage from Abies balsamea yielded 0.591% of an essential oil. Components were β-pinene (36%), bornyl acetate (14%), Δ3-carene (11%), limonene (11%), α-pinene (8%), camphene (6%), myrcene (2%), santene (1%), tricyclene (1%) and camphor, borneol, d-canadene, bisabolene, and terpinolene (all below 1%). \\ | "Canada balsam, also called Canada turpentine or balsam of fir, is a turpentine which is made from the resin of the balsam fir tree (Abies balsamea) of boreal North America. The resin, dissolved in essential oils, is a viscous, sticky, colourless or yellowish liquid that turns to a transparent yellowish mass when the essential oils have been allowed to evaporate... Due to its high optical quality and the similarity of its refractive index to that of crown glass (n=1.55), purified and filtered Canada balsam was traditionally used in optics as an invisible-when-dry glue for glass, such as lens elements... Canada balsam was also commonly used for making permanent microscope slides." \\ |
| | [[http://en.wikipedia.org/wiki/Canada_balsam]] |
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| | "Canada balsam comprises about 55% of diterpenoid acids, mainly abietic, neoabietic and |
| | palustric acids, 26% of volatile terpene hydrocarbons and about 19% of neutral diterpenoids |
| | of which the larger part consists of [[https://www.thegoodscentscompany.com/data/rw1491571.html|abienol]]." \\ |
| | [Gray, P. S., and J. S. Mills. "1109. The isolation of abienol from Canada Balsam, the oleoresin of Abies balsamea (L.) Mill." Journal of the Chemical Society (Resumed) (1964): 5822-5825] |
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| | Steam distillation of foliage from Abies balsamea yielded 0.59% of an essential oil. Components were β-pinene (36%), bornyl acetate (14%), Δ3-carene (11%), limonene (11%), α-pinene (8%), camphene (6%), myrcene (2%), santene (1%), tricyclene (1%) and camphor, borneol, d-canadene, bisabolene, and terpinolene (all below 1%). \\ |
| [The essential oil of //Abies balsamea// (L.) Mill., Shaw, A.C., Canadian Journal of Chemistry, Vol.31(2), 1953, 193-199] \\ | [The essential oil of //Abies balsamea// (L.) Mill., Shaw, A.C., Canadian Journal of Chemistry, Vol.31(2), 1953, 193-199] \\ |
| [[http://www.nrcresearchpress.com/doi/pdf/10.1139/v53-027]] | [[http://www.nrcresearchpress.com/doi/pdf/10.1139/v53-027]] |
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| | |{{:beta_pinene.jpg| β-pinene }} \\ β-pinene |{{:alpha_pinene.jpg| α-pinene }} \\ α-pinene |{{:carene_d3.jpg| δ-3-carene }} \\ δ-3-carene |{{:bornylacetate.jpg| bornyl acetate }} \\ bornyl acetate | |
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| "Monoterpenoids and sesquiterpene hydrocarbons of Abies balsamea cortical oleoresin (Canada balsam) were analyzed by a combination of chromatographic and spectroscopic methods. Monoterpene hydrocarbons (21%) were composed of β-pinene, α-pinene, β-phellandrene, limonene, 3-carene, myrcene and camphene (listed in order of decreasing percentages), and oxygenated monoterpenes (0·4%) contained 4,4-dimethyl-2-cyclohepten-1-one, linalool, bornyl acetate, methylthymol, citronellyl acetate, α-terpineol, piperitone, citronellal, borneol, citronellol, two unknowns, and geraniol. From the sesquiterpene hydrocarbon fraction (1·1%) were isolated: longifolene, β-bisabolene, longipinene, an unknown, sativene, cyclosativene, cis-α-bisabolene, β-himachalene, α-himachalene, β-caryophyllene, γ-humulene, farnesene, longicyclene, an unknown, and β-selinene. Both himachalenes have been identified for the first time in Pinaceae outside of Cedrus; their co-occurrence with γ-humulene, longifolene, longipinene and longicyclene supports the biosynthetic mechanism by which all of these compounds arise through initial 1/11 cyclization of tran-cis-farnesylphosphate." \\ | "Monoterpenoids and sesquiterpene hydrocarbons of Abies balsamea cortical oleoresin (Canada balsam) were analyzed by a combination of chromatographic and spectroscopic methods. Monoterpene hydrocarbons (21%) were composed of β-pinene, α-pinene, β-phellandrene, limonene, 3-carene, myrcene and camphene (listed in order of decreasing percentages), and oxygenated monoterpenes (0·4%) contained 4,4-dimethyl-2-cyclohepten-1-one, linalool, bornyl acetate, methylthymol, citronellyl acetate, α-terpineol, piperitone, citronellal, borneol, citronellol, two unknowns, and geraniol. From the sesquiterpene hydrocarbon fraction (1·1%) were isolated: longifolene, β-bisabolene, longipinene, an unknown, sativene, cyclosativene, cis-α-bisabolene, β-himachalene, α-himachalene, β-caryophyllene, γ-humulene, farnesene, longicyclene, an unknown, and β-selinene. Both himachalenes have been identified for the first time in Pinaceae outside of Cedrus; their co-occurrence with γ-humulene, longifolene, longipinene and longicyclene supports the biosynthetic mechanism by which all of these compounds arise through initial 1/11 cyclization of tran-cis-farnesylphosphate." \\ |
| [Composition and antibacterial activity of Abies balsamea essential oil., Pichette, A., Larouche, P.L., Lebrun, M., Legault, J., Phytotherapy Research, Vol.20(5), 2006, 371-373] | [Composition and antibacterial activity of Abies balsamea essential oil., Pichette, A., Larouche, P.L., Lebrun, M., Legault, J., Phytotherapy Research, Vol.20(5), 2006, 371-373] |
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| {{http://plantgenera.org/ILLUSTRATIONS_HD/82169.jpg?500}} \\ | The steam-distilled essential oil of the foliage contained β-pinene (33.5%), as main component, together with α-pinene (11.3%), δ-3-carene (14.0%), and bornyl acetate (10.0%). Minor components were camphene (5.7%), limonene (7.1%), and β-phellandrene (7.2%). Main components found in the hydrosol were α-terpineol, maltol, and bornyl acetate. \\ |
| Abies balsamea (L.) Miller [as Pinus balsamea L.] \\ | [Garneau, François-Xavier, et al. „Chemical Composition of the Hydrosol and the Essential Oil of Three Different Species of the Pinaceae Family: Picea glauca (Moench) Voss., Picea mariana (Mill.) BSP, and Abies balsamea (L.) Mill.“ Journal of Essential Oil Bearing Plants 15.2 (2012): 227-236] |
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| | Main volatiles found in the headspace of balsam fir needles powder were α-pinene, camphene, β-pinene, δ-3-carene, β-phellandrene, and bornyl acetate. Minor ones were tricyclene, β-myrcene, terpinolene, maltol, camphor, borneol, myrtenal, piperitone, longifolene, α-longipinene, β-caryophyllene, α-humulene, and α-bisabolene. \\ |
| | [Volatile compounds in the foliage of balsam fir analyzed by static headspace gas chromatography (HS-GC): An example of the spruce budworm defoliation effect in the boreal forest of Quebec, Canada., Caron, L., Deslauriers, A., Mshvildadze, V., Pichette, A., Microchemical Journal, 110, 2013, 587-590] |
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| | "Gas chromatography/mass spectrometry (GC/MS) of Abies balsamea, [[picea_mariana_mill._britton_et_al|Picea mariana]] and [[tsuga_canadensis_l._carr|Tsuga canadensis]] leaf essential oils assigned bornyl acetate as a major peak in A.balsamea and P.mariana, while isobornyl acetate was identified as the major peak in T.canadensis. Though these two isomers elute closely on GC, their characteristic mass spectra allow unequivocal structural assignment...\\ |
| | [Bernart, Matthew W. "Closely eluting bornyl and isobornyl acetates are chemotaxonomic markers in the Pinaceae by virtue of their unique mass spectra." American Journal of Essential Oils and Natural Products 4.2 (2016): 41-46] [[http://www.essencejournal.com/vol4/issue2/pdf/4-3-1.1.pdf]] |
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| | "The essential oil of balsam fir... [needles] is rich in monoterpenes, more than 95%. The dominant monoterpenes... are β-pinene (B), typically around 25-35%, and Δ3-carene (C) at 8-20% (with exceptions, see below). Some oxygenated compounds of this oil are bornyl acetate (F) typically between 5% and 9%, α-terpineol (D) between 0,1% and 1%, piperitone (E) between ∽0,1% and 1,2% and thymol (G) between traces and 0,3%..." \\ |
| | [[https://www.phytochemia.com/en/2017/12/20/oil-profiles-balsam-fir/]] |
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| | {{:pinus_balsamea.jpg?600}} \\ |
| | Abies balsamea (L.) Miller as Pinus balsamea L. \\ |
| Woodville, W., Hooker, W.J., Spratt, G., Medical Botany, 3th edition, vol. 5: t. 1 (1832) \\ | Woodville, W., Hooker, W.J., Spratt, G., Medical Botany, 3th edition, vol. 5: t. 1 (1832) \\ |
| [[http://plantgenera.org/species.php?id_species=629]] | [[http://plantgenera.org/species.php?id_species=629]] |
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| | {{:abies_balsamea_cones.jpg}} \\ |
| | Abies balsamea cones on Niapiskau island, Mingan Archipelago National Park Reserve, Quebec, Canada \\ [[https://commons.wikimedia.org/wiki/File:Abies_balsamea_cones_Niapiskau_02.jpg]] by Cephas 2012 [[https://creativecommons.org/licenses/by-sa/3.0/|CC BY-SA 3.0]] |
