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abelmoschus_moschatus [2017/09/03 23:39]
andreas |
abelmoschus_moschatus [2019/08/11 10:54]
andreas |
| "The seeds have a sweet, flowery, heavy fragrance similar to that of musk (hence its specific epithet moschātus, scientific Latin for ‘musk’)." \\ | "The seeds have a sweet, flowery, heavy fragrance similar to that of musk (hence its specific epithet moschātus, scientific Latin for ‘musk’)." \\ |
| [[http://en.wikipedia.org/wiki/Abelmoschus_moschatus]] | [[http://en.wikipedia.org/wiki/Abelmoschus_moschatus]] |
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| | The macrocyclic musk compound (Z)‐5‐Tetradecen‐14‐olide, together with (Z)‐5‐dodecenyl acetate, and (Z)‐5‐tetradecenyl acetate have been isolated from the absolute oil of Hibiscus abelmoschus L. \\ |
| | [Maurer, Bruno, and Alfred Grieder. "(Z)‐5‐Tetradecen‐14‐olide, a New Macrocyclic Lactone, and Two Unsaturated Straight Chain Acetates from Ambrette Seed Absolute." Helvetica Chimica Acta 60.4 (1977): 1155-1160] |
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| Main components of the monoester fraction of ambrette (Hibiscus abelmoschus seeds) were (E,E)-2,6-farnesyl acetate (70%), (Z,E)-2,6-farnesyl acetate (6%), [[http://webbook.nist.gov/cgi/cbook.cgi?ID=123-69-3|(Z)-7-hexadecen-16-olide]] (natural ambrettolide, 12%) and (Z)-9-octadecen-18-olide (oxacyclononadec-10-en-2-one, 4.5%). \\ | Main components of the monoester fraction of ambrette (Hibiscus abelmoschus seeds) were (E,E)-2,6-farnesyl acetate (70%), (Z,E)-2,6-farnesyl acetate (6%), [[http://webbook.nist.gov/cgi/cbook.cgi?ID=123-69-3|(Z)-7-hexadecen-16-olide]] (natural ambrettolide, 12%) and (Z)-9-octadecen-18-olide (oxacyclononadec-10-en-2-one, 4.5%). \\ |
| "These compounds are localized in the outer layers of the seed coat, but are not epicuticular. They are deposited in the seed coat after seed coat dry weight accumulation has essentially stopped, but at the same time as embryo dry weight and neutral lipid are increasing." \\ | "These compounds are localized in the outer layers of the seed coat, but are not epicuticular. They are deposited in the seed coat after seed coat dry weight accumulation has essentially stopped, but at the same time as embryo dry weight and neutral lipid are increasing." \\ |
| [Seed coat components of Hibiscus abelmoschus., Nee, T.Y., Cartt, S., Pollard, M.R., Phytochemistry, 25(9), 1986, 2157-2161] | [Seed coat components of Hibiscus abelmoschus., Nee, T.Y., Cartt, S., Pollard, M.R., Phytochemistry, 25(9), 1986, 2157-2161] |
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| | |{{:farnesylacetate.jpg|(E,E)-farnesylacetate}} \\ (E,E)-farnesylacetate |{{:ambrettolide_nat.png|(Z)-7-hexadecen-16-olide}} \\ (Z)-7-hexadecen-16-olide \\ //(natural ambrettolide)// | |
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| The commercial extract or essential oil (hydrodistillation) from ambrette seeds is long been used in perfumery for its sweet, floral-musky, winelike odor. A mechanic separation of the water-soaked seed coats followed by alcoholic extraction and liquid-liquid extraction of the oleoresin obtained after removal of the alcoholic solvent with pentan or hexan, and removing fatty acids over a short column, led to an extract (0.24-0.29%) with sweet-smelling and lasting odor, almost free from fatty acids. Main components of this extract were decyl acetate (5.7%), dodecyl acetate (5.1%), farnesene (9.6%), (Z)-5-tetradecen-14-olide (1.3%), (Z)-5-tetradecenyl acetate (1.2%), (Z,E)-2,6-farnesyl acetate (3.8%), (E,E)-2,6-farnesyl acetate (50.4%), (Z)-7-hexadecen-16-olide (9.3%), (Z)-9-octadecen-18-olide (1.2%).\\ | The commercial extract or essential oil (hydrodistillation) from ambrette seeds is long been used in perfumery for its sweet, floral-musky, winelike odor. A mechanic separation of the water-soaked seed coats followed by alcoholic extraction and liquid-liquid extraction of the oleoresin obtained after removal of the alcoholic solvent with pentan or hexan, and removing fatty acids over a short column, led to an extract (0.24-0.29%) with sweet-smelling and lasting odor, almost free from fatty acids. Main components of this extract were decyl acetate (5.7%), dodecyl acetate (5.1%), farnesene (9.6%), (Z)-5-tetradecen-14-olide (1.3%), (Z)-5-tetradecenyl acetate (1.2%), (Z,E)-2,6-farnesyl acetate (3.8%), (E,E)-2,6-farnesyl acetate (50.4%), (Z)-7-hexadecen-16-olide (9.3%), (Z)-9-octadecen-18-olide (1.2%).\\ |
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| {{:abelmoschus_moschatus.jpg?500}} \\ | {{:abelmoschus_moschatus.jpg?600}} \\ |
| Hibiscus moschatus (Medik.) Salisb. as Abelmoschus moschatus Medik. \\ | Hibiscus moschatus (Medik.) Salisb. as Abelmoschus moschatus Medik. \\ |
| Moninckx, J., Moninckx atlas, vol.4 t.25 (1682-1709) \\ | Moninckx, J., Moninckx atlas, vol.4 t.25 (1682-1709) \\ |
| [[http://www.plantillustrations.org/species.php?id_species=508]] | [[http://www.plantillustrations.org/species.php?id_species=508]] |
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| | {{https://upload.wikimedia.org/wikipedia/commons/thumb/2/24/Abelmoschus_moschatus_%28Malvaceae%29_%2829680066960%29.jpg/1024px-Abelmoschus_moschatus_%28Malvaceae%29_%2829680066960%29.jpg}} \\ |
| | Abelmoschus moschatus, Ecuador (2016), Author: yakovlev.alexey from Moscow |
| | [[https://creativecommons.org/licenses/by-sa/2.0/de/|CC BY-SA 2.0]] [[https://commons.wikimedia.org/wiki/File:Abelmoschus_moschatus_(Malvaceae)_(29680066960).jpg#/media/File:Abelmoschus_moschatus_(Malvaceae)_(29680066960).jpg|Wikimedia Commons]] |
