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--- lavandula_angustifolia_mill [2022/09/03 16:59] – andreas
+++ lavandula_angustifolia_mill [2024/08/02 10:14] (aktuell) – andreas
@@ Zeile 23: / Zeile 23: @@
 Linalool (40.9%) and linalyl acetate (33.9%) were quantitatively the main components in lavender oil. Linalool was found almost optically pure (88.0% ee; jasmine tea 82.6%) as (R)-(-). "Only [[http://www.leffingwell.com/chirality/linalool.htm|(R)-(−)-linalool]] elicited a significant decrease in heart rate (P < 0.05) and an increase in high-frequency component in comparison with the controls, and produced calm and vigorous mood states." \\
 [Sedative effects of the jasmine tea odor and (R)-(−)-linalool, one of its major odor components, on autonomic nerve activity and mood states., Kuroda, K., Inoue, N., Ito, Y., Kubota, K., Sugimoto, A., Kakuda, T., Fushiki, T., European journal of applied physiology, 95(2-3), 2005, 107-114]
+"(3E,5Z)-undeca-1,3,5-triene also occurs in olfactorly significant amounts in, for example, angelica root oil, lavender oil, celery herb oil, the scent of fresh pineapple, mandarin, peppermint, and many Coryanthes species." \\
+[Meaningful Scents around the World, R.Kaiser, 2006, 58; R.Kaiser internal Givaudan files]
 "...two monoterpene synthases (LaLIMS and LaLINS) and one sesquiterpene synthase (LaBERS) were cloned from lavender leaves and flowers. LaLIMS catalyzed the formation of (R)-(+)-limonene, terpinolene, (1R,5S)-(+)-camphene, (1R,5R)-(+)-α-pinene, β-myrcene and traces of α-phellandrene. The proportions of these products changed significantly when Mn2+ was supplied as the cofactor instead of Mg2+. The second enzyme LaLINS produced exclusively (R)-(−)-linalool, the main component of lavender essential oil. LaBERS transformed farnesyl diphosphate and represents the first reported trans-α-bergamotene synthase. " \\
@@ Zeile 30: / Zeile 33: @@
 [Essential oil composition of Lavandula angustifolia Mill. cultivated in the mid hills of Uttarakhand, India., Verma, Ram S., et al., Journal of the Serbian Chemical Society Vol.75(3), 2010, 343-348]
-Over 90% of lavender oils is composed of only 12 components occuring at > 1% (with (R)-(-)-linalool and (R)-linalyl acetate together up to 70%), a further 26 compounds are present in amounts of 0.1-1.0%, and the remaining 3% of the oil is compromised of 250 trace compounds with great structural diversity. The undeca-1,3,5-trienes (galbanolenes, 0.02%) and (3E,5Z,8Z)-undeca-1,3,5,8-tetraene (0.004%) contribute considerably to the scent impression of the oil due to their low thresholds and characteristic odor qualities (intense galbanum). Further olfactorly important trace components are Z-jasmone, methyl jasmonate, β-ionone, β-damascenone, coumarin, emthyl salicylate, 2-hydroxycuminal, eugenol, guaiacol, as well as 2-acetylpyridine and 5-isoprenyl-2-methylpyridine. \\
+Over 90% of lavender oils is composed of only 12 components occuring at > 1% (with (R)-(-)-linalool and (R)-linalyl acetate together up to 70%), a further 26 compounds are present in amounts of 0.1-1.0%, and the remaining 3% of the oil is compromised of 250 trace compounds with great structural diversity. The undeca-1,3,5-trienes (galbanolenes, 0.02%) and (3E,5Z,8Z)-undeca-1,3,5,8-tetraene (0.004%) contribute considerably to the scent impression of the oil due to their low thresholds and characteristic odor qualities (intense galbanum). Further olfactorly important trace components are Z-jasmone, methyl jasmonate, β-ionone, β-damascenone, coumarin, methyl salicylate, 2-hydroxycuminal, eugenol, guaiacol, as well as 2-acetylpyridine and 5-isoprenyl-2-methylpyridine. \\
 [Scent and Chemistry, Günther Ohloff, Wilhelm Pickenhagen, Philip Kraft, Wiley-VCH, 2012, 242-247]