Benutzer-Werkzeuge

Webseiten-Werkzeuge


robinia_pseudoacacia_l

Unterschiede

Hier werden die Unterschiede zwischen zwei Versionen angezeigt.

Link zu dieser Vergleichsansicht

Beide Seiten der vorigen Revision Vorhergehende Überarbeitung
Nächste Überarbeitung
Vorhergehende Überarbeitung
Letzte Überarbeitung Beide Seiten der Revision
robinia_pseudoacacia_l [2017/03/30 12:38]
andreas
robinia_pseudoacacia_l [2017/03/30 12:42]
andreas
Zeile 6: Zeile 6:
 [[http://en.wikipedia.org/wiki/Robinia_pseudoacacia]] [[http://en.wikipedia.org/wiki/Robinia_pseudoacacia]]
  
-Major constituents of the vacuum headspace concentrate from the flowers were 2-aminobenzaldehyde (31.5%), methyl anthranilate (14.6%), linalool/phenylethanol (18% together), nerolidol (5.3%), α-farnesene (5.1%), and (E)-ocimene (4.4%). "It should be noted that the mass spectrum of 2-aminobenzaldehyde is very clos to that of formanilide proposed by most of the commercial mass spectra librabries." \\+Major constituents of the vacuum headspace concentrate from the flowers were 2-aminobenzaldehyde (31.5%), methyl anthranilate (14.6%), linalool/phenylethanol (18% together), nerolidol (5.3%), α-farnesene (5.1%), and (E)-ocimene (4.4%). Phenylnitroethane, (Z)-3-hexenyl benzoate and 1-octen-3-ol were minor odorants. \\ 
 +"It should be noted that the mass spectrum of 2-aminobenzaldehyde is very close to that of formanilide proposed by most of the commercial mass spectra librabries." \\
 [Joulain, D. „Study of the fragrance given off by certain springtime flowers.“ Progress in essential oil research (1986): 57-67]  [Joulain, D. „Study of the fragrance given off by certain springtime flowers.“ Progress in essential oil research (1986): 57-67] 
 +
 +| {{:methylanthranilate.jpg| methyl anthranilate}} \\ methyl anthranilate | {{:2-aminobenzaldehyde.jpg| 2-aminobenzaldehyde}} \\ 2-aminobenzaldehyde | {{:carene_d3.jpg| δ-3-carene }} \\ δ-3-carene | {{:linalool.jpg| linalool}} \\ linalool | 
  
 "The floral fragrance headspace of living Robinia pseudoacacia was trapped on Tenax tube cartridges using air as the carrier. After solvent elution, the major components identified using GC/MS were [[http://www.thegoodscentscompany.com/data/rw1014471.html|δ-3-carene]] (54.6%), linalool (21%), (Z)-β-farnesene (3.0%) and anthranilate aldehyde (3.9%)." \\ "The floral fragrance headspace of living Robinia pseudoacacia was trapped on Tenax tube cartridges using air as the carrier. After solvent elution, the major components identified using GC/MS were [[http://www.thegoodscentscompany.com/data/rw1014471.html|δ-3-carene]] (54.6%), linalool (21%), (Z)-β-farnesene (3.0%) and anthranilate aldehyde (3.9%)." \\
 [Characterization of black locust floral fragrance. Kamdem, D. P., Gruber, K., Barkman, T., Gage, D. A., Journal of Essential Oil Research, 6(2), 1994, 199-200] [Characterization of black locust floral fragrance. Kamdem, D. P., Gruber, K., Barkman, T., Gage, D. A., Journal of Essential Oil Research, 6(2), 1994, 199-200]
- 
-| {{:carene_d3.jpg| δ-3-carene }} \\ δ-3-carene | {{:linalool.jpg| linalool}} \\ linalool | {{:2-aminobenzaldehyde.jpg| 2-aminobenzaldehyde}} \\ 2-aminobenzaldehyde \\ (anthranilate aldehyde) |  
  
 Feeding experiments with 13C- and fluorine-labelled precursors revealed that the biosynthesis of 2-aminobenzaldehyde in flowers of Robinia pseudoacacia and Philadelphus coronarius is realized by transformation of anthranilic acid to indole followed by oxidative ring opening and hydrolysis of the resulting N-formyl-2-aminobenzaldehyde. \\ Feeding experiments with 13C- and fluorine-labelled precursors revealed that the biosynthesis of 2-aminobenzaldehyde in flowers of Robinia pseudoacacia and Philadelphus coronarius is realized by transformation of anthranilic acid to indole followed by oxidative ring opening and hydrolysis of the resulting N-formyl-2-aminobenzaldehyde. \\
robinia_pseudoacacia_l.txt · Zuletzt geändert: 2022/06/07 11:51 von andreas