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eutrema_japonicum_miq._koidz [2021/08/16 13:09]
andreas angelegt
eutrema_japonicum_miq._koidz [2022/10/21 11:37]
andreas
Zeile 15: Zeile 15:
 The main volatile components of E.wasabi grown in Yunnan were identified as 1,6-hexane diisothiocyanate (30.7%) and allyl isothiocyanate (17.1%)  with GC-MS. \\ The main volatile components of E.wasabi grown in Yunnan were identified as 1,6-hexane diisothiocyanate (30.7%) and allyl isothiocyanate (17.1%)  with GC-MS. \\
 [Study on Volatile Components Of Yunnan Eutrema Wasabi Maxim., LU, Li-he, et al. Yunnan Chemical Technology, Vol.5, 2011, 4] [Study on Volatile Components Of Yunnan Eutrema Wasabi Maxim., LU, Li-he, et al. Yunnan Chemical Technology, Vol.5, 2011, 4]
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-{{:allylitc.jpg|allyl isothiocyanate}} allyl isothiocyanate 
  
 Total content of isothiocyanates of Japanese horseradish rhizome grown in New Zealand was 2067mg/kg fresh weight, with allyl isothiocyanate (AITC, 1937 mg/kg) as the main component. Minor components present were 3-butenyl isothiocyanate (43 mg/kg), 4-pentenyl isothiocyanate (47 mg/kg), sec-butyl isothiocyanate (18 mg/kg), isopropyl isothiocyanate (12 mg/kg) and 5-hexenyl isothiocyanate (7 mg/kg). \\ Total content of isothiocyanates of Japanese horseradish rhizome grown in New Zealand was 2067mg/kg fresh weight, with allyl isothiocyanate (AITC, 1937 mg/kg) as the main component. Minor components present were 3-butenyl isothiocyanate (43 mg/kg), 4-pentenyl isothiocyanate (47 mg/kg), sec-butyl isothiocyanate (18 mg/kg), isopropyl isothiocyanate (12 mg/kg) and 5-hexenyl isothiocyanate (7 mg/kg). \\
 [Comparison of flavour compounds in wasabi and horseradish., Sultana, T., Savage, G. P., McNeil, D. L., Porter, N. G., Clark, B., Journal of Food Agriculture & Environment, Vol.1(2), 2003, 117-121] [[http://www.coppersfolly.co.nz/v1/research/comparison2.pdf]] [Comparison of flavour compounds in wasabi and horseradish., Sultana, T., Savage, G. P., McNeil, D. L., Porter, N. G., Clark, B., Journal of Food Agriculture & Environment, Vol.1(2), 2003, 117-121] [[http://www.coppersfolly.co.nz/v1/research/comparison2.pdf]]
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 +| {{:allylitc.jpg|allyl isothiocyanate}} \\ allyl isothiocyanate \\ //(pungent mustard)// | {{:octa15diene3one.jpg|(Z)-octa-1,5-dien-3-one}} \\ (Z)-octa-1,5-dien-3-one \\ //(green geranium)// | {{:3methyl24nonandione.jpg|3-methyl-2,4-nonanedione}} \\ 3-methyl-2,4-nonanedione \\ //(fruity hay)// | {{:pyrazine_2meo3isopropyl.png|2-methoxy-3-isopropylpyrazine}} \\ 2-methoxy-3-isopropylpyrazine \\ //(earthy green)//|
  
 "Freshly grated wasabi aroma was investigated by aroma extract dilution analysis. At the highest flavor dilution factors of 1024 and 256, ten odorants were detected as odor-active compounds: allyl isothiocyanate, (Z)-1,5-octadien-3-one, 4-pentenyl isothiocyanate, 5-hexenyl isothiocyanate, 3-methyl-2-butene-1-thiol, 2-isopropyl-3-methoxypyrazine, 3-methyl-2,4-nonanedione, cis-3-methyl-4-decanolide, 6-(methylthio) hexyl isothiocyanate, and vanillin. To determine the absolute configuration of cis-3-methyl-4-decanolide in wasabi, the stereoisomers of 3-methyl-4-decanolide were synthesized from optically active γ-decalactone. Finally, the absolute configuration of cis-3-methyl-4-decanolide in wasabi was determined as (3R,4R)-3-methyl-4-decanolide by chiral GC-MS. Sensory analysis revealed that the (3R,4R)-3-methyl-4-decanolide constitutes an essential part of fresh wasabi aroma." \\ "Freshly grated wasabi aroma was investigated by aroma extract dilution analysis. At the highest flavor dilution factors of 1024 and 256, ten odorants were detected as odor-active compounds: allyl isothiocyanate, (Z)-1,5-octadien-3-one, 4-pentenyl isothiocyanate, 5-hexenyl isothiocyanate, 3-methyl-2-butene-1-thiol, 2-isopropyl-3-methoxypyrazine, 3-methyl-2,4-nonanedione, cis-3-methyl-4-decanolide, 6-(methylthio) hexyl isothiocyanate, and vanillin. To determine the absolute configuration of cis-3-methyl-4-decanolide in wasabi, the stereoisomers of 3-methyl-4-decanolide were synthesized from optically active γ-decalactone. Finally, the absolute configuration of cis-3-methyl-4-decanolide in wasabi was determined as (3R,4R)-3-methyl-4-decanolide by chiral GC-MS. Sensory analysis revealed that the (3R,4R)-3-methyl-4-decanolide constitutes an essential part of fresh wasabi aroma." \\
eutrema_japonicum_miq._koidz.txt · Zuletzt geändert: 2023/12/07 13:02 von andreas